The ejection came after James argued with referee Kane Fitzgerald about a call he disagreed with. He was then given a technical foul.
That was obviously not what James wanted to hear because he kept arguing and was quickly tossed.
James had 21 points, 12 rebounds, six assists and five steals before he was ejected.
The Cavaliers were up by 23 at the time of his ejection.
James had played in 1,081 games coming into Tuesday without being ejected.
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